Overview
The flash point of a material is the "lowest liquid temperature at which, under certain standardized conditions, a liquid gives off vapours in a quantity such as to be capable of forming an ignitable vapour/air mixture". (EN 60079-10-1)
The flash point is sometimes confused with the autoignition temperature, the temperature that causes spontaneous ignition. The fire point is the lowest temperature at which the vapors keep burning after the ignition source is removed. It is higher than the flash point, because at the flash point vapor may not be produced fast enough to sustain combustion. Neither flash point nor fire point depends directly on the ignition source temperature, but ignition source temperature is far higher than either the flash or fire point, and can increase the temperature of fuel above the usual ambient temperature to facilitate ignition.
Fuels
The flash point is a descriptive characteristic that is used to distinguish between flammable fuels, such as petrol (also known as gasoline), and combustible fuels, such as diesel.
It is also used to characterize the fire hazards of fuels. Fuels which have a flash point less than are called flammable, whereas fuels having a flash point above that temperature are called combustible.
From Wikipedia (CC BY-SA 4.0).