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Topic
potassium oxide
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Overview
Potassium oxide (KO) is an ionic compound of potassium and oxygen. It is a base. This pale yellow solid is the simplest oxide of potassium. It is a highly reactive compound that is rarely encountered. Some industrial materials, such as fertilizers and cements, are assayed assuming the percent composition that would be equivalent to K2O.
Production
Potassium oxide is produced from the reaction of oxygen and potassium; this reaction affords potassium peroxide, K2O2. Treatment of the peroxide with potassium produces the oxide:
K2O2 + 2 K -> 2 K2O
Alternatively and more conveniently, K2O is synthesized by heating potassium nitrate with metallic potassium:
2KNO3 + 10K -> 6K2O + N2 (^)
Other possibility is to heat potassium peroxide at 500 °C which decomposes at that temperature giving pure potassium oxide and oxygen.